Chlorido{N-[2-(diphenylphosphanyl)benzyl]-1-(pyridin-2-yl)methanamine-κP}gold(I)
نویسندگان
چکیده
In the title compound, [AuCl(C(25)H(23)N(2)P)], the Au(I) atom is in a typical almost linear coordination environment defined by phosphane P and Cl atoms [bond angle = 175.48 (4)°]. Helical supra-molecular chains along the b axis and mediated by N-H⋯Cl hydrogen bonds feature in the crystal packing.
منابع مشابه
Chlorido{N-[(E)-2-(diphenylphosphanyl)benzylidene]-2-(thiophen-2-yl)ethanamine-κP}gold(I)
The title compound, [AuCl(C(25)H(22)NPS)], crystallizes with two independent mol-ecules in the asymmetric unit in which the thio-phene fragments are disordered over two sets of sites with 0.537 (10):0.463 (10) and 0.701 (9):0.299 (9) occupancy ratios. In both cases, the thio-phene ring is rotated by approximately 180° for the second component. Important geometrical parameters include Au-P = 2.2...
متن کاملChlorido{[(E)-2-(diphenylphosphanyl)benzylidene](furan-2-ylmethyl)amine-κP}gold(I)
In the title complex, [AuCl(C24H20NOP)], the ligand has N, P and O electron-donating atoms but the Au(I) atom is coordinated only by the 'soft' P atom and an additional Cl atom in an almost linear fashion. Important geometrical parameters include Au-P = 2.2321 (13) Å, Au-Cl = 2.2820 (13) Å and P-Au-Cl = 176.49 (5)°. The furan ring is disordered over two positions in a 0.51 (2):0.49 (2) ratio.
متن کاملChlorido{N-[2-(diphenylphosphanyl)benzylidene]-2,6-diisopropylaniline-κP}gold(I) chloroform 0.25-solvate
The asymmetric unit of the title compound, [AuCl(C31H32NP)]·0.25CHCl3, contains two independent complex mol-ecules and half a chloro-form solvent mol-ecule, which is disordered across an inversion center. The Au(I) ions are each coordinated in a slightly distorted linear environment, with P-Au-Cl angles of 177.20 (4) and 178.54 (4)°.
متن کاملCrystal structures of three mercury(II) complexes [HgCl2 L] where L is a bidentate chiral imine ligand
The crystal structures of three complexes [HgCl2 L] were determined, namely, (S)-(+)-di-chlorido-[1-phenyl-N-(pyridin-2-yl-methyl-idene)ethyl-amine-κ(2) N,N']mercury(II), [HgCl2(C14H14N2)], (S)-(+)-di-chlorido-[1-(4-methyl-phen-yl)-N-(pyridin-2-yl-methyl-idene)ethyl-amine-κ(2) N,N']mercury(II), [HgCl2(C15H16N2)], and (1S,2S,3S,5R)-(+)-di-chlorido-[N-(pyridin-2-yl-methyl-idene)isopino-camph-eyl-...
متن کامل[5-(Pyridin-2-yl)-1H-tetrazole-κ2 N 4,N 5]bis(triphenylphosphane-κP)copper(I) tetrafluoridoborate
In the title Cu(I) compound, [Cu(C6H5N5)(C18H15P)2]BF4, the Cu(I) cation is N,N'-chelated by a 5-(pyridin-2-yl)-1H-tetra-zole ligand and coordinated by two triphenyl-phosphane ligands in a distorted tetra-hedral geometry. The tetra-zole and pyridine rings are essentially coplanar [dihedral angle = 4.1 (3)°]. The tetra-fluoridoborate anion links to the complex cation via an N-H⋯F hydrogen bond.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011